RECENT ADVANCES IN NTC THICK FILM THERMISTOR PROPERTIES AND APPLICATIONS

Obrad Aleksic, Pantelija M. Nikolić

DOI Number
10.2298/FUEE1703267A
First page
267
Last page
284

Abstract


An introduction to thermal sensors and thermistor materials is given in brief. After that novel electrical components such as thick film thermistors and thermal sensors based on them are described: Custom designed NTC thermistor pastes based on nickel manganite NiM2O4 micro/nanostructured powder were composed and new planar cell-based (segmented) constructions were printed on alumina. The thick film segmented thermistors were used in novel thermal sensors such as anemometers, water flow meters, gradient temperature sensor of the ground, and other applications. The advances achieved are the consequence of previous improvements of thermistor material based on nickel manganite and modified nickel manganite such as Cu0.2Ni0.5Zn1.0Mn1.3O4 and optimization of thick film thermistor geometries for sensor applications. The thermistor powders where produced by a solid state reaction of MnCO3, NiO, CuO, ZnO powders mixed in proper weight ratio. After calcination the obtained thermistor materials were milled in planetary ball mils, agate mills and finally sieved by 400 mesh sieve. The powders were characterized by XRD and SEM. The new thick film pastes where composed of the powders achieved, an organic vehicle and glass frit. The pastes were printed on alumina, dried and sintered and characterized again by XRD, SEM and electrical measurements. Different thick film thermistor constructions such as rectangular, sandwich, interdigitated and segmented were printed of new thermistor pastes. Their properties such as electrical resistance of the thermistor samples where mutually compared. The electrode effect was measured for all mentioned constructions and surface resistance was determined. It was used for modeling and realizations of high, medium and low ohmic thermistors with different power dissipation and heat loss. Finally all the results obtained lead to thermal sensors based on heat loss for measuring the air flow, water flow, temperature gradient and heat transfer from the air to the ground.


Keywords

Metal oxide thermistors, thick film thermistor geometries, thick film thermistor sensors and systems

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References


P. R. N. Childs, J. R. Greenwood, C. A. Long, “Review of temperature measurement”, Review Scientific Instrumentation, vol. 71, no. 8, pp. 2959-2965, 2000.

T. D. Mc Gee, Principles and Methods of Temperature Measurement, John Wiley,1988, pp. 2-21

N.G. Lewis, M. Randall, Thermodynamics, 2 nd edition, McGraw-Hill, New York, 1961, pp. 378-379.

D. Sherry, “Thermoscopes, thermometers, and the foundations of measurement”, Studies in History and Philosophy of Science, vol. 42, pp. 509–524, 2011.

P. Coates, D. Lowe, The Fundamentals of Radiation Thermometers, Chapter 1:The Basis of Temperature Measurement, CRC Press 2016, pp. 10-30.

M. J. Moran, H. N. Shapiro, Fundamentals of Engineering Thermodynamics, Chapter 1, John Wiley & Sons, 2006, pp. 10-25.

J. G. Webster, H. Eren, Measurement, Instrumentation and Sensor Handbook, Thermal and temperature measurement, Chapter 7, 2nd edition, CRC Press 2014, pp. 65-78.

B. L. Hunt, “The early history of the thermocouple”, Platinum Metals Rev., vol. 8, no. 1, pp. 23-28, 1964.

Y.S. Touloukian, D.P. DeWitt P.D., Thermophysical Properties of Matter, TPRC Series, vol. 7 - Thermal Radiative Properties, Metallic Element and Alloys, IFI/Plenum NY, 1970, pp. 159-168.

R.E. Bentley, Handbook of temperature measurement, vol. 3: Theory and practice of thermoelectric thermometry. Springer-Verlag Singapore Pte. Ltd., 1998, pp. 24-36.

R.A. Felice, “Pyrometry for liquid metals”, Advanced Materials & Processes, vol.166 (7), ASM International, pp. 31-33, 2008.

R. P. Benedict, Fundamentals of Temperature, Pressure, and Flow Measurements, Third Edition, Chapter 8. Optical Pyrometry, John Wiley 1984, pp. 130-145.

E.D. Macklean, Thermistors, Electrochem. Pub., Glasgow, 1979, pp. 5-22.

F. J. Hyde, Thermistors, First Edition, Published by ILIFFE, 1971, pp. 2-15.

D. R. White, “Temperature errors in linearizing resistance networks for thermistors”, International Journal of Thermophysics, vol. 36, no. 12, pp. 3404–3420, 2015.

P. Umadevi, C. L. Nagendra, “Preparation and characterization of transition metal oxide micro-thermistors and their application to immersed thermistor bolometer infrared detectors”, Sensors and Actuators A: Physical, vol. 96, no. 2–3, pp. 114-124, 2002.

H. Zumbahlen, Linear Circuits Design Handbook, Chapter 3-2 Temperature sensors: Thermistors, Analog Devices -Newnes, 2008, pp. 231-240.

W. Kester, J. Bryant, W. Jung, Sensor Signal Conditioning, Temperature Sensors, Chapter 7, Analog Devices, pp. 1-38, 2000.

D. D. Pollock, Thermocouples: theory and properties, CRC Press, 1991, pp. 181- 195.

B. Gosselin Jr, “NTC thermistors versus voltage output IC temperature sensors”, Texas Instruments ECN: 04/02/2013, pp. 1-3.

T. Kuglestadt, “Semiconductor Temperature Sensors Challenge Precision RTDs and Thermistors in Building Automation”, Texas Instruments: Application Report: SNAA267–04 2015, pp. 2-10.

T.G. Nanov, S.P. Yordanov, Ceramic Sensors: Technology and Applications, Chapter 5 Thermistors, CRC Press, 1996, pp. 193-203.

C. Ma, Y. Liu, Y. Lu, H. Qian, “Preparation and electrical properties of Ni0.6Mn2.4xTixO4 NTC ceramics”, Journal of Alloys and Compounds, vol. 650, pp. 931-935, 2015.

J. Park, “Microstructural and electrical properties of Y0.2Al0.1Mn0.27−xFe0.16Ni0.27−x(Cr2x)Oy for NTC thermistors”, Ceramics International, vol. 41, no. 5, pp. 6386-6390, 2015.

O. Shpotyuk, A. Kovalskiy, O. Mrooz, L. Shpotyuk, V. Pechnyo, S. Volkov, “Technological modification of spinel-based CuxNi1−x−yCo2yMn2−yO4 ceramics”, Journal of the European Ceramic Society, vol. 21, no. 11-12, pp. 2067–2070, 2001.

R. Metz, “Electrical properties of N.T.C. thermistors made of manganite ceramics of general spinel structure: Mn3−x−x′MxNx′O4 (0 ⩽ x + x′ ⩽ 1; M and N being Ni, Co or Cu). Aging phenomenon study”, Journal of Materials Science, vol. 35, pp. 4705–4711, 2000.

R.C. Buchanan, Ceramic Materials for Electronics: Processing, Properties and Applications (Electrical Engineering & Electronics), Marcel Dekker Inc; Enlarged 2nd edition, 1986, pp. 125-162.

M. Vakiv, O. Shpotyuk, O. Mrooz, I. Hadzaman, “Controlled thermistor effect in the system CuxNi1-x-yCo2yMn2-yO4”, Journal of the European Ceramic Society, vol. 21, pp. 1783–1785, 2001.

E. S. Na, U. G. Paik, S. C. Choi, “The effect of a sintered microstructure on the electrical properties of a Mn-Co-Ni-O thermistor”, Journal of Ceramic Processing Research, vol. 2 (1), pp. 31- 34, 2001.

H. Zhang, A. Chang, C. Peng, “Preparation and characterization of Fe3+-doped Ni0.9Co0.8Mn1.3-xFexO4 (0 < x < 0.7) negative temperature coefficient ceramic materials”, Microelectronic Engineering, vol. 88, no. 9, pp. 2934–2940, 2011.

M. L. M. Sarrión, M. M. Sánchez, “Preparation and characterization of thermistors with negative temperature coefficient, NixMn3–xO4(1

C. Ma, Y. Liu, Y. Lu, H. Gao, H. Qian, J. Ding, “Preparation and characterization of Ni0.6Mn2.4O4 NTC ceramics by solid-state coordination reaction”, J Materials Science: Materials in Electronics, vol. 24, no. 12, pp. 5183–5188, 2013.

D. Fang, C. G. Lee, B. H. Koo, “Preparation of Ultra-Fine FeNiMnO4 Powders and Ceramics by a Solid-State Coordination Reaction”, Metals and Materials International, vol. 13, no. 2, pp. 165-170, 2007.

K. Park, I.H. Han, “Effect of Al2O3 addition on the microstructure and electrical properties of Mn0,37Ni0,3(Co0,33-xAlx)O4 (0  x 0.03) NTC thermistors”, Materials Science and Engineering, B vol. 119, pp. 55-60, 2005.

P. Ouyang, H. Zhang, Y. Zhang, J. Wang, Z. Li, “Zr substituted SnO2-based NTC thermistors with wide applications temperature range and high property stability”, Journal of Materials Science: Materials in Electronics, vol. 26, no. 8, pp. 6163–6169, 2015.

R. K. Kamat, G. M. Naik, “Thermistors – in search of new applications, manufacturers cultivate advanced NTC techniques”, Sensor Review, vol. 22, no. 4, pp. 334 - 340, 2002.

T. Yang, B. Zhang, Q. Zhao, P. Luo, A. Chang, “New high temperature NTC thermistors based on the Mg(Al1−xCrx)2O4 ceramics”, Journal of Alloys and Compounds, vol. 685, pp. 287–293, 2016.

W. Lee and J. Park, “NTC Thermistors of Y-Al-Mn-Fe-Ni-Cr-O Ceramics for Wide Temperature Range Measurement”, In Proceedings of the 8th International Conference on Sensing Technology, Sep. 2-4, 2014, Liverpool, pp. 307-310.

B. Zhang, Q. Zhao, A. Chang, H. Yan, Y. Wu, “MgAl2O4–LaCr0.5Mn0.5O3 composite ceramics for high temperature NTC thermistors”, J Mater Science: Materials in Electronics, vol. 24, no. 11, pp. 4452–4456, 2013.

S. Subhanarayan, S. K. S. Parashar, S. M. Ali, “CaTiO3 nano ceramic for NTCR thermistor based sensor application”, Journal of Advanced Ceramics, vol. 3, no. 2, pp. 117–124, 2014.

A. Feltz, R. Krigel, W. Polzl, “Sr7Mn4O15 ceramics for high temperature NTC thermistors”, Journal of Material Science Letters, vol. 18, no. 20, pp. 1693–1695, 1999.

K. Park, “Microstructure and electrical properties of Ni1.0Mn2-xZrxO4 (0  x  1.0) negative temperature coefficient thermistors”, Materials Science and Engineering, B vol. 104, no. 1-2, pp. 9-14, 2003.

W. Waslaluddin, D. G. Syarif, “Effect of MnO2 Addition on Characteristics of Fe2TiO5 Ceramics for NTC Thermistor Utilizing Commercial and Local Iron Oxide”, Journal of The Australian Ceramic Society, vol. 49, no. 2, pp. 141– 147, 2013.

Y. Luo, X. Liu, “High temperature NTC BaTiO3-based ceramic resistors”, Materials Letters, vol. 59, no. 29-3, pp. 3881 – 3884, 2005.

W. Lee and J. Park, “NTC Thermistors of Y-Al-Mn-Fe-Ni-Cr-O Ceramics for Wide Temperature Range Measurement”, In Proceedings of the 8th International Conference on Sensing Technology, Sep. 2-4, 2014, Liverpool, UK, pp. 307-310.

C. Yuan, X. Liu, M. Liang, C. Zhou, H. Wang, “Electrical properties of Sr–Bi–Mn–Fe–O thick-film NTC thermistors prepared by screen printing”, Sensors and Actuators, vol. A 167, pp. 291–296, 2011.

R. Schmidt, A.W. Brinkman, “Electrical properties of screen-printed NiMn2O4+δ”, Journal of the European Ceramic Society, vol. 25, no. 12, pp. 3027–3031, 2005.

X. Xiong, J. Xu, P. Zhao, L. Wang, L. Bian, F. Xu, J. Zhang, A. Chang, “Structural and electrical properties of thick film thermistors based on perovskite La–Mn–Al–O”, Ceramics International, Part B, vol. 40, no. 7, pp. 10505-10510, 2014.

Y. Yang, C. Yuan, G. Chen, T. Yang, Y. Luo, C. Zhou, “Effect of Ba0.5Bi0.5Fe0.9Sn0.1O3 addition on electrical properties of thick-film thermistors”, Transactions of Nonferrous Metals Society of China, vol. 25, no. 12, pp. 4008-4017, 2015.

C.L. Yuan, X.Y. Liu, C.R. Zhou, J.W. Xu, B. Li, “Electrical properties of lead-free thick film NTC thermistors based on perovskite-type BaCoIIxCoIII2xBi1 − 3xO3”, Materials Letters, vol. 65, no. 5, pp. 836-839, 2011.

C. Yuan, X. Wu, J. Huang, X. Liu, B. Li, “Electrical properties of thick film NTC thermistors based on SrFe0.9Sn0.1O3−δ ”, Solid State Sciences, vol. 12, no. 12, pp. 2113-2119, 2010.

S. Jagtap, S. Rane, S. Gosavi, D. Amalnerkar, “Low temperature synthesis and characterization of NTC powder and its ‘lead free’ thick film thermistors”, Microelectronic Engineering, vol. 87, no. 2, pp.104-107, 2010.

S. Jagtap, S. Rane, S. Gosavi, D. Amalnerkar, “Preparation, characterization and electrical properties of spinel-type environment friendly thick film NTC thermistors”, Journal of the European Ceramic Society, vol. 28, no. 13, pp. 2501-2507, 2008.

K. Park, “Structural and electrical properties of FeMg0.7Cr0.6Co0.7−xAlxO4 (0≤x≤0.3) thick film NTC thermistors”, Journal of the European Ceramic Society, vol. 26, no. 6, pp. 909–914, 2006.

K. Park, D.Y. Bang, “Electrical properties of NiMn-Co(Fe) oxide thick film NTC thermistors”, Journal of Materials Science: Materials in Electronics, vol. 14, pp. 81-87, 2003.

O.S. Aleksić, P.M. Nikolić, D.G. Vasiljević-Radović, M.D. Luković, S.Djurić, M.N. Simić, V.Ž. Pejović, K.T. Radulović, D. Vujošević, D. Luković, “Properties of Thick Film NTC Layers Based on NanometricMn,Co,Fe-Oxide Powder Mixture”, Printed in book Science of sintering: Current problems and New Trends, editor M.M.Ristić, SANU press, 2003, pp. 427-32.

S. Savic, O. S. Aleksic, P. M. Nikolic, D. T. Lukovic, “Geometrical and electrical properties of NTC polycrystalline thermistors vs. changes of sintering parameters”, Science of Sintering, vol. 38, no. 3, pp. 223-229, 2006.

M. V. Nikolic, K. M. Paraskevopoulos, O. S. Aleksic, T. T. Zorba, S. M. Savic, V. D. Blagojevic, D. T. Lukovic, P. M. Nikolic, “Far infrared reflectance of sintered nickel-manganite samples used as negative temperature coefficient thermistors”, Materials Research Bulletin, vol. 42, pp. 1492-1498, 2007.

S. M. Savic, G. M. Stojanovic, M. V. Nikolic, O. S. Aleksic, D. T. Lukovic-Golic. P. M. Nikolic, “Electrical and transport properties of nickel manganite obtained by Hall effect measurements”, Journal of Materials Science: Materials in Electronics, vol. 20, no. 3, pp. 242-247, 2009.

S. M. Savic, M. V. Nikolic, O. S. Aleksic, M. Slankamenac, M. Zivanov, P. M. Nikolic, “Intrinsic resistivity of sintered nickel manganite vs. powder activation time and density”, Science of Sintering, vol. 40, no. 1, pp. 27-32, 2008.

O.S. Aleksić, P.M. Nikolić, D. Luković, K. Radulović, D. Vasiljević-Radović, P. Nikolidis, “Investigation of the thermal diffusivity for thick film NTC layers by photoacoustic technique”, Microelectronics International, vol. 21, no. 1, pp. 10-14, 2004.

O. S. Aleksic, P. M. Nikolic, D. Lukovic, S. Savic, D. Vasiljevic-Radovic, K. Radulovic, L. Lukic, A. Bojicic, D. Urosevic, “Investigation of the thermal diffusivity of thick film NTC layers obtained with the photoacoustic method”, Journal de Physique IV, France, vol. 125, pp. 431-433, June 2005.

S. M. Savić, O. S. Aleksić, M. V. Nikolić, D. T. Luković, V. Ž. Pejović, P. M. Nikolić, “Thermal diffusivity and electron transport properties of NTC samples obtained by photoacoustic method”, Materials Science and Engineering B, vol. 131, no. 1-3, pp. 216-221, 2006.

O. S. Aleksic, M. V. Nikolic, M. D. Lukovic, N. Nikolic, B. Radojcic, M. Radovanovic, Z. Z. Djuric, M. Mitric, P. M. Nikolic, “Preparation and characterization of Cu and Zn modified nickel manganite NTC powders and thick film thermistors”, Mater Sci. Eng. B, vol. 178, no. 3, pp. 202-210, 2013.

O.S. Aleksić, P.M. Nikolić, D.M. Todorović, “Analysis and Synthesis of Thick Film Resistor Using EGET Principles”, Hybrid Circuits, (Microelectronics International), vol. 5, no. 3, pp. 20-23, 1988.

O. S. Aleksic, B. M. Radojcic, R. M. Ramovic, “Modeling and simulation of NTC thick film thermistor geometries”, Microelectronics International, vol. 24, no. 1, pp. 27-34, 2007.

O. S. Aleksic, V. Dj. Maric, Lj. D. Zivanov, A. B. Menicanin, “A novel approach to modeling and simulation of NTC thick-film segmented thermistors for sensor applications”, IEEE Sensors Journal, vol. 7, no. 10, pp. 1420-1428, 2007.

V. Dj. Maric, M. D. Lukovic, Lj. D. Zivanov, O. S. Aleksic, A. B. Menicanin, “EM simulation analysis of optimal performance thick film segmented thermistors versus materials characteristics selection”, IEEE Transactions on Instrumentation and Measurement, vol. 57, no. 11, pp. 2568-2575, 2008.

J. S. Steinhart, S.R. Hart, “Calibration curves for thermistors”, Deep-Sea Research and Oceanographic Abstracts, vol.15, no. 4, pp. 497-503, 1968.

S. Rudtsch, C. von Rohden, “Calibration and self-validation of thermistors for high-precision temperature measurements”, Measurement, vol. 76, pp. 1-6, December 2015.

C. Chen, “Evaluation of resistance–temperature calibration equations for NTC thermistors”, Measurement, vol. 42, no. 7, pp. 1103-1111, 2009.

S.B. Stanković, P.A. Kyriacou, “The effects of thermistor linearization techniques on the T-history characterization of phase change materials”, Applied Thermal Engineering, vol. 44, no. 11, pp. 78-84, 2012.

O.S. Aleksić, “Three dimensional anemometer comprising thick film segmented thermistors”, (WO-2007-014400), Published in Patent Gazette, International Bureau WIPO, Geneve, Swiss, 1.02.2007, http://patentscope.wipo.int/seach, Google type: WO-2007-014400, pp. 1-18.

A.B Menicanin, O.S Aleksic, M.V Nikolic, S.M Savic, B.M Radojcic, “Novel uniaxial anemometer containing NTC thick film segmented thermistors”, Proceedings of the 26th International Conference of Microelectronics 11-14 May 2008 (IEEE MIEL), pp. 349-352.

O. S. Aleksic, S. M. Savic, M. D. Lukovic, K. T. Radulovic, L. S. Lukic, “Segmented thermistors printed by NTC nanometric paste and applied in volume air-flow sensors”, Materials Science Forum: Recent Developments in Advanced Materials and Processes, vol. 518, pp. 247-252, 2006.

O. S. Aleksic, P. M. Nikolic, K. M. Paraskevopoulos, “Volume air flow sensors based on NTC thick film segmented thermistors”, Microelectronics International, vol. 23, no. 3, pp. 14-18, 2006.

O. S. Aleksic, S. M. Savic, M. V. Nikolic, L. Sibinoski, M. D. Lukovic, “Micro flow sensor for water using NTC thick film segmented thermistors”, Microelectronics International, vol. 26, no. 3, pp. 30-34, 2009.

M. V. Nikolic, B. M. Radojcic, O. S. Aleksic, M. D. Lukovic, P. M. Nikolic, “A thermal sensor for water using self-heated NTC thick-film segmented thermistors”, IEEE Sensors Journal, vol. 11, no. 8, pp.1640-1645, 2011.

O. S. Aleksic, M. V. Nikolic, M. D. Lukovic, Z. I. Stanimirovic, I. P. Stanimirovic, L. Z. Sibinoski, “The response of a heat loss flowmeter in a water pipe under changing flow conditions”, IEEE Sensors Journal, vol. 16, no. 9, pp. 2935-2941, 2016.


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